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101.
Cation exchange experiments (ammonium acetate and cation resin) on celadonite-smectite vein minerals from three DSDP holes demonstrate selective removal of common Sr relative to Rb and radiogenic Sr. This technique increases the Rb/Sr ratio by factors of 2.3 to 22 without significantly altering the age of the minerals, allowing easier and more precise dating of such vein minerals. The ages determined by this technique (site 261—121.4 ±1.6 m.y.; site 462A—105.1 ±2.8 m.y.; site 516F—69.9 ±2.4 m.y.) are 34, 54 and 18 m.y. younger, respectively, than the age of crust formation at the site; in the case of site 462A, the young age is clearly related to off-ridge emplacement of a massive sill/flow complex. At the other sites, either the hydrothermal circulation systems persisted longer than for normal crust (10–15 m.y.), or were reactivated by off-ridge igneous activity.

Celadonites show U and Pb contents and Pb isotopic compositions little changed from their basalt precursors, while Th contents are significantly lower. Celadonites thus have unusually high alkali/U,Th ratios and low Th/U ratios. If this celadonite alteration signature is significantly imprinted on oceanic crust as a whole, it will lead to very distinctive Pb isotope signatures for any hot spot magmas which contain a component of aged subducted recycled oceanic crust.

Initial Sr isotope ratios of ocean crust vein minerals (smectite, celadonite, zeolite, calcite) are intermediate between primary basalt values and contemporary sea water values and indicate formation under seawaterdominated systems with effective water/rock ratios of 20–200.  相似文献   

102.
A numerical mesoscale meteorological model has been applied over the heterogeneous terrain of central Israel in order to study wind energy characteristics of three typical synoptic situations. The supportive nature of this method for observationally oriented wind energy studies has been emphasized. Mesoscale forcing effects on the availability of wind energy and on the exponent, p, in the vertical wind power law are evaluated.  相似文献   
103.
A sampling technique has been developed for increasing the information gathered during routine monitoring of impingement at water intake structures. Samples from impingement catches on traveling screens were taken from the sluiceway of the Brunswick Steam Electric Plant near Southport, North Carolina during the screen wash process so as to divide the catch into vertical catch components. Each component represented 1.2 m of the water column. Results showed differences in day and night vertical distributions of impinged organisms according to the spatial preferences of each species. Impingement during daytime was lower than during night. Impingement of surface-oriented species during daytime occurred at mid-depth, midwater species near the bottom, and bottom species were seldom impinged. During the night surface-oriented species were impinged at the surface, midwater species at mid-depth, and bottom species near the bottom. Residue (animals and debris) which remained within the screen wash system from collection of the previous sample, and those organisms which became impinged on the screens during retrieval of the sample, were used to calculate the rate of “continuous impingement” on the traveling screens. These rates were compared to the impingement catch in order to determine biases in the vertical catch components. Comparison of these rates indicated that impingement estimates determined by routine monitoring methods may under-estimate true impingement rates for certain species. We have concluded that this sampling technique for monitoring impingement at intake structures will increase knowledge of the local biologic system while minimizing the cost of obtaining the information. The technique will also aid in pinpointing specific impingement problems which may be corrected through modifications to the design of the intake structure.  相似文献   
104.
Three groups of Sn-W veins occur in the contact aureole of composite granitic plutons South of Bragança (Trás-os-Montes, Portugal). Thin layers of calcic quartzites with or without scheelite are interbedded in the Ordovician and Silurian metamorphic country-rocks. Could they represent synsedimentary preconcentrations and a likely source for the W-deposits? The geologic features and the trace-elements distribution (W, Sn, Be, B, Li, F, Rb) in the metasedimentary and granitic rocks support the following conclusions: 1) the scheelite-bearing calcic quartzites are tactites, that occur only in the contact aureole of the granites; 2) the dynamo-metamorphic country-rocks are weakly enriched in W and impoverished in Sn compared to the "clarke" values; 3) the trace-elements concentration is higher in the contact aureole (X 2) than outwards; 4) the quartzites are scheelite-bearing only in the vicinity of the wolframite veins. Thus, scheelite appears related to mineralizing hydrothermal processes. Through their chemical composition and their mechanical properties, the calcic quartzites appear as traps for a tungsten mainly foreign to the metamorphic rocks close to the granites. Thus, the source of W lies deeper in lower crust levels or in the upper-mantle.  相似文献   
105.
While the chemical structure of the earth's mantle is probably rather complex, multi-box models have been used as a first approximation to evaluate this structure. Most commonly, a three-box model is used, involving the continental crust, the upper mantle and the lower mantle. The depleted upper mantle and the continental crust are assumed to represe1nt complementary reservoirs, related by crust formation processes occurring during geologic history.Here we investigate the Rb/Sr and Sm/Nd isotopic systematics of several three-box models, using mass balance equations and the definition of the mean age of the reservoirs. The geochemical uniqueness of the models, chosen from a large family of possible models, is evaluated from elementary graph theory, and these models are then solved using a total inversion approach. This paper (Part I) describes the methodology of the procedure; the companion paper (Part II) discusses the application of this approach to multi-box mantle models.  相似文献   
106.
107.
It is suggested that leakage currents flow across Devon, north of Exeter, from large-scale electric-current systems induced in the Atlantic Ocean by the geomagnetic variations incident on the Atlantic Ocean from the ionosphere. This model can account for the variation with period of the contribution of induced current flow to the differences in the magnetic H variations of period > 30 s observed at Exeter and Sidmouth.  相似文献   
108.
The latest or n ewest version of the char acteristic an alysis (NCHARAN)computer program offers the exploration geologist a wide variety of options for integrating regionalized multivariate data. The options include the selection of regional cells for characterizing deposit models, the selection of variables that constitute the models, and the choice of logical combinations of variables that best represent these models. Moreover, the program provides for the display of results which, in turn, makes possible review, reselection, and refinement of a model. Most important, the performance of the above-mentioned steps in an interactive computing mode can result in a timely and meaningful interpretation of the data available to the exploration geologist. The most recent application of characteristic analysis has resulted in the possible discovery of economic sulfide mineralization in the Grong area in central Norway. Exploration data for 27 geophysical, geological, and geochemical variables were used to construct a mineralized and a lithogeochemical model for an area that contained a known massive sulfide deposit. The models were applied to exploration data collected from the Gjersvik area in the Grong mining district and resulted in the identification of two localities of possible mineralization. Detailed field examination revealed the presence of a sulfide vein system and a partially inverted stratigraphic sequence indicating the possible presence of a massive sulfide deposit at depth.  相似文献   
109.
Alteration of basaltic glass to palagonite is characterized by a nearly isomolar exchange of SiO2, Al2O3, MnO, MgO, CaO, Na2O, P2O5, Zn, Cu, Ni, Cr, Hf, Sc, Co and REE for H2O and K2O, whilst TiO2 and FeO are passively accumulated during removal of the remaining cations. The network forming cations Al and Si are removed from the glass in proportion to the gain in Ti and Fe, whilst the other cations do not show a significant relationship to the amount of Ti and Fe accumulation. Sr isotopic data show that during palagonite formation approximately 85% of the basaltic Sr is lost to the hydrous solutions and 40% of seawater Sr is added to the glass, yielding an average loss of the same order of magnitude as of the network forming cations. Losses and gains of oxides yield an average increase of +105% TiO2.K, Rb, and Cs show high increases, but KRb and KCs ratios indicate two different alteration processes: (1) formation of palagonite involves a drastic decrease in these ratios, indicating structural similarities between palagonite and smectite; (2) surface alteration of glass is characterized by an increase in KRb and KCs ratios, probably best interpreted as sorption of alkalies in ratios approximating those of seawater.The total fluxes involved in alteration of glass in the upper portion of the oceanic crust are estimated from the modal abundance of palagonite in the oceanic crust and the abundance of the vein materials smectite and carbonate. Smectite and carbonates act as a sink for a significant portion of the elements liberated up during alteration of basaltic glass except for Na and Al, which are probably taken up by zeolites and/or albite, possibly hidden in the macroscopic estimate of carbonate. Formation of the observed quantity of secondary phases requires additional sources for Si, Fe. Ca and K. K is provided in excess from the inflowing seawater at reasonable water/rock ratios. The remaining excess Ca, Si and Fe required may be derived by alteration of interstitial glass and breakdown of anorthite rich plagioclase and titano-magnetite, and/or by supply of deeper seated metamorphic reactions.  相似文献   
110.
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